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Keggin杂多化合物上异丁烷选择氧化研究进展
Selective Oxidation of Isobutane Over Keggin-Type Heteroply Compounds:Recent Development
【摘要】 研究发现,对异丁烷选择性氧化成甲基丙烯酸的催化剂都为Keggin结构杂多化合物.通过回顾近年来Keggin结构杂多化合物用于异丁烷选择氧化制甲基丙烯酸的研究状况及可能的反应机理,对此反应可能的改进方案和应用前景作出了预测.
【Abstract】 It has been found that the most active and selective catalysts are those based on Keggin-type heteroply compounds.This paper summarized the studies on the selective oxidation of isobutane over Keggin-type heteroply compounds and some proposed reaction mechanisms in recent years.The application perspectives of Keggin-type heteroply compounds as catalysts for these reactions and some probable probale activity-enhancemetns were put forward.
【关键词】 异丁烷;
Keggin结构;
杂多化合物;
甲基丙烯酸;
选择氧化;
【Key words】 isobutane; Keggin-type; heteroply compounds; methacrylic acid; selective oxidation;
【Key words】 isobutane; Keggin-type; heteroply compounds; methacrylic acid; selective oxidation;
【基金】 湖南省教育厅科研课题资助项目(01C26)
- 【文献出处】 吉首大学学报(自然科学版) ,Journal of Jishou University(Natural Science Edition) , 编辑部邮箱 ,2003年03期
- 【分类号】O621.25
- 【被引频次】6
- 【下载频次】82