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Synthesis and Characterization of a Novel Perfluorinated Ionomer Polymer Containing Sulfonimide Functionality

Synthesis and Characterization of a Novel Perfluorinated lonomer Polymer Containing Sulfonimide Functionality

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【作者】 朱士正； 章云祥； 金桂芳； DesMarteau； Darryl D；

【Author】 ZHU, Shi-Zheng ZHANG, Yun-Xiang JIN, Gui-FangDesMarteau, Darryl D. Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China Department of Chemistry, H. L. Hunter Chemistry Laboratory Clemson University, Clemson, SC 29634-1905

【机构】 Shanghai Institute of Organic Chemistry； Chinese Academy of Sciences； Shanghai 200032； China； Department of Chemistry； H. L. Hunter Chemistry Laboratory Clemson University； Clemson； SC 29634-1905； SC 29634-1905；

【摘要】 <正> The novel perfluorinated vinyl ether containing sulfonimidefunctionality CF2=CFORSO2NHSO2CF3 was synthesized bymultiple reaction steps. It could be copolymerized with tetraflu-oroethylene by radox initiator to give a novel perfluorinatedionomer polymer. Its physical and chemical properties werestudied.

【Abstract】 The novel perfluorinated vinyl ether containing sulfonimide functionality CF2 = CFORfSO2NHSO2CF3 was synthesized by multiple reaction steps. It could be copolymerized with tetraflu-oroethylene by radox initiator to give a novel perfluorinated ionomer polymer. Its physical and chemical properties were studied.

【关键词】 perfluorinated vinyl ether； sulfonimide； copolymer-ization； ionomer； resin；
【Key words】 perfluorinated vinyl ether； sulfonimide； copolymer-ization； ionomer； resin；
【基金】 Project supported by the National Natural Science Foundation of China(Nos.20032010,20072049).
  • 【文献出处】 Chinese Journal of Chemistry ,中国化学(英文版) , 编辑部邮箱 ,2003年07期
  • 【分类号】O631
  • 【下载频次】4
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