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聚丙烯催化合金的结晶行为研究

Studies on Crystallization Behavior of Polypropylene Catalloys

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【作者】 林忠华彭懋郑强

【Author】 LIN Zhong-Hua, PENG Mao, ZHENG Qiang * (Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China)

【机构】 浙江大学高分子科学与工程学系浙江大学高分子科学与工程学系 杭州310027杭州310027杭州310027

【Abstract】 Non-isothermal crystallization behavior of molten polypropylene catalloys(PP-c) was studied by using differential scanning calorimetry(DSC). Besides, crystallization process and spherulite morphology were observed through polarized optical microscopy. Compared with pure polypropylene(PP), the crystallization peak temperature(t p c) of PP-c shifted to a higher temperature, and the value of t p c became bigger with the increase of ethylene component in PP-c. The spherulitic geometrical dimension of PP-c decreased distinctly, and the number of spherulite augmented obviously. It is believed that the ethylene component acts as the heterogeneous nucleation agent in PP-c.

【基金】 国家杰出青年基金 (批准号 :5 0 12 5 3 12 );国家重点基础规划项目 (批准号 :G19990 6480 3 )资助
  • 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2003年10期
  • 【分类号】O632
  • 【被引频次】5
  • 【下载频次】112
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