节点文献
聚丙烯催化合金的结晶行为研究
Studies on Crystallization Behavior of Polypropylene Catalloys
【Abstract】 Non-isothermal crystallization behavior of molten polypropylene catalloys(PP-c) was studied by using differential scanning calorimetry(DSC). Besides, crystallization process and spherulite morphology were observed through polarized optical microscopy. Compared with pure polypropylene(PP), the crystallization peak temperature(t p c) of PP-c shifted to a higher temperature, and the value of t p c became bigger with the increase of ethylene component in PP-c. The spherulitic geometrical dimension of PP-c decreased distinctly, and the number of spherulite augmented obviously. It is believed that the ethylene component acts as the heterogeneous nucleation agent in PP-c.
【关键词】 聚丙烯催化合金(PP-c);
聚丙烯(PP);
乙烯组分;
结晶行为;
【Key words】 Polypropylene catalloy(PP-c); Polypropylene(PP); Ethylene component; Crystallization behavior;
【Key words】 Polypropylene catalloy(PP-c); Polypropylene(PP); Ethylene component; Crystallization behavior;
【基金】 国家杰出青年基金 (批准号 :5 0 12 5 3 12 );国家重点基础规划项目 (批准号 :G19990 6480 3 )资助
- 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2003年10期
- 【分类号】O632
- 【被引频次】5
- 【下载频次】112