【摘要】 通过杯 [6]芳烃六乙酸乙酯与多乙烯多胺进行氨解反应 ,合成了系列酰胺型杯 [6]芳烃聚合物 ,并研究了它们的阳离子吸附性能 .发现它们对软金属离子具有较高的吸附容量 ,其吸附能力与聚合物中杯芳烃的含量成正比 ,说明杯芳烃单元在吸附过程中有着决定性的作用 ,聚合物 3c对 Ag+有较好的选择性吸附能力 .更多还原

【Abstract】 Reacting calixarene hexaesters with poly(ethyleneimine), a series of calixamides-based polymers were obtained for the first time. It is found that they show high absorption capacities towards soft cations comparing to hard cations, and the absorption abilities enhanced with the increasing of calixarene content, which may indicates the cavity of calixarene plays crucial role in absorption. Polymer 3c shows good selective absorption capability towards Ag+ among the tested cations.更多还原