【摘要】 选用2-乙基己基琥珀酸钠(AOT)/异辛烷、聚氧乙烯烷基苯基醚(Triton-X100或OP)/正辛醇/环己烷以及十六烷基三甲基溴化铵(CTAB)/氯仿/正辛醇三种不同类型的表面活性剂形成的反胶束体系为模板进行苯胺聚合.系统地讨论了苯胺与过硫酸铵的物质的量的比、反应时间、氧化剂滴加速率、反应温度、微水相酸浓度及表面活性剂浓度等因素对于反应表观收率及电导率的影响.更多还原

【Abstract】 Polymerization of aniline was performed in three different reversed micelle systems as template,namely,AOT(bis(2-ethylhexyl)sodium slfosuccinate)/iso-octane,OP (p-octy1-polydthylene glycel phenylether)/caprylie alcohol/cyclohexane and CTAB (hexaclecylerimethylammonium bromide)/chloroform/caprylie alcohol.Polymerization conditions including molar radio of aniline and the oxidant,reaction time,drop speed of the oxidant,reaction temperature,concentration of the acid and the surfactants on the apparent yield and conductivity were discussed.更多还原