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激光束作用下Al-Ti-C活化粉料中的化学反应(英文)

Chemical Reactions in Activated Al-Ti-C Powder Mixture under Action of Laser Beam

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【作者】 黄延禄马乃恒邹德宁梁工英苏俊义

【Author】 Huang Yanlu1, Ma Naiheng2, Zou Dening1, Liang Gongying1,3, Su Junyi1 (1. School of Mechanical Engineering, Xian Jiaotong University, Xian 710049, China) (2. School of Materials Science and Engineering, Shanghai Jiaotong University,Shanghai 200030, China) (3. State Key Laboratory of Laser Technology, Huazhong University of Science and Technology, Wuhan 430074, China)$$$$

【机构】 西安交通大学,上海交通大学材料科学与工程学院,西安交通大学,西安交通大学,西安交通大学 陕西西安710049,上海200030,陕西西安710049,陕西西安710049华中科技大学激光技术国家重点实验室,湖北武汉430074,陕西西安710049

【摘要】 在激光扫描涂覆Al-Ti-C活化粉料层的铝合金试样过程中,突然停止激光发射,以在激光束前面形成合成反应过程中不同阶段所产生的组织,判断所发生的化学反应,即先发生3Al+Ti→Al3Ti反应,形成块状Al3Ti;以后再发生Al3Ti+C→TiC+3Al反应,形成大量TiC颗粒。将实验与数值模拟相结合,采用试错法求得:3Al+Ti→Al3Ti的反应温度为650℃,Al3Ti+C→TiC+3Al的反应温度为810℃。

【Abstract】 In the experiment, Al specimen coated with a layer of activated Al Ti C powder mixture was scanned by a laser beam. In order to remain the microstructures in the surface region ahead of laser spot, the laser emission was broken off during the scanning. The microstructures of different distances from laser spot were composed of the products formed in different stages of synthesis reaction. According to the constituents in the microstructures, the following conclusions can be deduce: firstly, the reaction 3Al+Ti→Al3Ti occurs and forms block like structure of Al3Ti, and then the reaction Al3Ti+C→TiC+3Al takes place and produces a mass of TiC spherules. Combining the experiment with numerical simulation of temperature field and using trial and error procedure, the reaction temperatures are determined as follows: it is 650°C for reaction 3Al+Ti→Al3Ti, and 810°C for Al3Ti+C→TiC+3Al.

【基金】 SupportedbytheNationalNaturalScienceFoundationofChina(50271051)
  • 【文献出处】 稀有金属材料与工程 ,Rare Metal Materials and Engineering , 编辑部邮箱 ,2003年12期
  • 【分类号】TG174.44
  • 【被引频次】4
  • 【下载频次】96
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