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造纸废水的混凝-水解-接触氧化处理技术

Coagulation-Anaerobic Hydrolysis-Aerobic Process for Chlorinated Bleaching Effluents Treament

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【作者】 陈元彩; 陈中豪; 詹怀宇; 付时雨; 管秀琼;

【Author】 Chen Yuancai 1 Chen Zhonghao 1 Zhan Huaiyu 1 Fu Shiyu 2 Guan Xiuqiong 1 (1.State Key Lab of Pulp&Paper Engineering,South China University of Technology,Guangzhou,Guangdong Province,510640;2.Lab of Cellulose and Lignocellulosi

【机构】 华南理工大学制浆造纸工程国家重点实验室; 中国科学院广州化学所纤维素化学重点实验室; 华南理工大学制浆造纸工程国家重点实验室 广州; 510640; 广州; 510650; 广;

【摘要】 研究了以混凝、厌氧酸化、生物接触氧化一体化反应器处理含氯漂白废水,水力停留时间为15h时,整个系统CODCr、BOD5、AOX、毒性值去除率分别达88.1%、81%、98.4%、92%。混凝单元主要去除大分子氯代有机物;厌氧单元通过还原脱氯及酸性水解,使氯代有机物得到了基本的去除;好氧单元对CODCr有较高的去除率。红外光谱的分析结果表明:废水中既有木素又有纤维素和半纤维素,虽然漂白废水厌氧处理效果不如好氧处理,但厌氧、好氧联合处理可有效地提高处理效果。

【Abstract】 The coagulation-anaerobic acidification-aerobic reactor was studied for the treatment of CEH bleaching effluents,and the removal efficiencies of COD Cr ,BOD 5 ,AOX and toxicity were88.1%,81%,98.4%and92%respectively with15h retention time.The removal in the floc-unit was mainly high molecule weight chlorinated compound;Most of chlorinated compounds were removed by reduced dechlorina-tion and acidified hydrolysis in anaerobic unit;The higher removal efficiency of COD Cr was found in aerobic unit.FTIR results indicated that there were lignin,cellulose and hemicellulose in the effluents.The combination of anaerobic and aerobic process could effectively im-prove the COD Cr removal rate.

【基金】 教育部重点科研项目(99284);中科院广州纤维素化学开放实验室开放基金(K-140);华南理工大学自然科学基金(E5-302-161)资助项目。
  • 【文献出处】 中国造纸 ,China Pulp & Paper , 编辑部邮箱 ,2002年03期
  • 【分类号】X793
  • 【被引频次】8
  • 【下载频次】241
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