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对硝基苯胺在表面活性剂改性黄土中的吸附行为

Sorption behavior of p-nitroaniline on surfactant-modified loess soils

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【作者】 周文军姜梅展惠英杨瑞强陈慧刘国光

【Author】 ZHOU Wen-jun, JIANG Mei, ZHAN Hui-ying, YANG Rui-qiang, CHEN Hui, LIU Guo-guang (College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, Gansu, China) (College of Chemistry and Environmental Science. Henan Normal Univer

【机构】 西北师范大学化学化工学院河南师范大学化学与环境科学学院 甘肃兰州730070甘肃兰州730070河南新乡453002

【摘要】 研究了用阳离子表面活性剂改性的黄土对水中对硝基苯胺的吸附行为以及2,4-二氯苯酚对对硝基苯胺吸附行为的影响.结果表明,天然黄土和改性黄土对对硝基苯胺的等温吸附曲线均符合Freundlich方程;改性后的黄土对对硝基苯胺的吸附能力明显强于天然黄土,改性黄土的吸附能力主要取决于阳离子表面活性剂的加入量;2,4-二氯苯酚与对硝基苯胺存在竞争吸附;2,4-二氯苯酚的非离子形态对对硝基苯胺在改性黄土上的吸附量的影响大于它的离子形态;对硝基苯胺在阳离子表面活性剂改性后的黄土上的吸附行为符合双模式吸附理论

【Abstract】 The sorption behaviors of p-nitroaniline in the loess soils that were individually modified by a cation surfactant-hexadecyltrimethylammonium bromide( HDTMAB) are studied while the influences of 2 ,4-dichlomphenol are investigated. The sorption isotherms of p-nitroaniline on natural and HDTMAB-modified loess soils agrees to Freundlichequation. The capacities of the HDTMAB-modified loess soils on p-nitroaniline are apparently higher than the natural loess soils when the sorption capacities increases proportionally with the adding quantity of the surfactants. However, with the adding of 2, 4-dichbomphenol in soil matrix, the sorption capacities of the HDTMAB-modified loess soils on pnitroaniline are reduced. The neutral forms of 2, 4-dichborophenol tend to take higher effects on the adsorbed amount of p-nitroaniline by HDTMAB-modified loess soils than the anion form. The sorption behavior of p-nitroaniline on HDTMAB-modified loess soils accords with dual-mode sorption mechanism for soil organic matter.

【关键词】 对硝基苯胺表面活性剂黄土吸附竞争
【Key words】 p-nitroanilinesurfactantloess soilsorptioncompetition
【基金】 国家自然科学基金资助项目(29977015);河南省环境科学与工程重点学科开放实验室科研资助项目(2001)
  • 【文献出处】 西北师范大学学报(自然科学版) ,Journal of Northwest Normal University(Natural Science Edition) , 编辑部邮箱 ,2002年02期
  • 【分类号】X131.3
  • 【被引频次】8
  • 【下载频次】125
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