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乙烯基吡咯烷酮/磺酸甜菜碱两性单体共聚物水凝胶的溶胀行为
Swelling Behavior of Poly (N-vinyl-2-pyrrolidone-co-sulfobetaine) Hydrogel
【摘要】 合成了乙烯基吡咯烷酮/磺酸甜菜碱两性单体共聚物水凝胶,探讨了时间、温度和外加盐浓度对凝胶溶胀行为的影响.与单一聚乙烯基毗咯烷酮凝胶不同,引入磺酸甜菜碱单体后得到的新型水凝胶同时具有温度和盐双重敏感特性,且其吸水性有明显改善.
【Abstract】 Poly (N-vinyl-2-pyrrolidone-co-sulfobetaine) hydrogel and poly (N-vinyl-2-pyrrolidone) hydrogel were prepared by free radical polymerization in the presence of N, N’-methylene-bisacrylamide. The influence of external stimuli such as temperature, ionic strength and time on the equilibrium swelling behavior of the gels were investigat- ed. Unlike individual PVP gel, the copolymer gel was characteristic of higher swelling ratio, both thermo - and salt -responsive behavior.
【关键词】 共聚物水凝胶;
溶胀比;
温度敏感;
反聚电解质效应;
【Key words】 copolymeric hydrogel; swelling ratio; thermosensitivity; antipolyelectrolyte behavior;
【Key words】 copolymeric hydrogel; swelling ratio; thermosensitivity; antipolyelectrolyte behavior;
【基金】 国家自然科学基金资助项目(29804011);高等学校骨干教师资助计划资助项目
- 【文献出处】 中山大学学报(自然科学版) ,Acta Scientiarum Naturalium Universitatis Sunyatseni , 编辑部邮箱 ,2001年05期
- 【分类号】O631.1
- 【被引频次】15
- 【下载频次】275