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高效一体化脱硫脱硝催化剂

High Effective deSO - deNO Integrated Catalysts*

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【作者】 张昭良马骏杨锡尧

【Author】 Zhang Zhao- Liang Ma Jun Yang Xi- Yao (College of Chemistry and Molecular Engineering,Peking University,Beijing 100871)

【机构】 北京大学化学与分子工程学院!北京100871

【Abstract】 TiO2,CoS and SnO2 respectively by itself is inactive for the reduction of SO2 or/and NO by CO;however,we discovered that both TiO2- CoS (1:1 mass ratio) and TiO2- SnO2 (1:1 mass ratio) composite compounds are very active for such reactions,at 300- 350℃ ,the conversion of SO2 to S,NO to N2 are over 90% ,and the selectivity towards S or N2 are over 95% .These mean that there are synergism effects between TiO2 and CoS,TiO2 and SnO2.It was confirmed by XRD characterization that TiO2 and CoO,TiO2 and SnO2 transform to rutile after calcinations at 500℃ ,however,individual TiO2(anatase) can only transform to rutile up to 900℃ .Therefore ,it is suggested that the synergism effects must be related to these composites comcound which exist as rutile structure.The study of the reaction mechanism and model of active phase are underway.

【关键词】 脱硫脱硝TiO2-CoS催化剂SnO2催化剂金红石
【Key words】 deSO_xdeNO_xTiO2- CoS catalystsTiO2- SnO2 catalystsRutile
【基金】 国家重点基础研究发展规划项目 (G19990222);国家自然科学基金资助项目 (20077002)
  • 【文献出处】 物理化学学报 ,Acta Physico-chimica Sinica , 编辑部邮箱 ,2001年06期
  • 【分类号】O643.3
  • 【被引频次】20
  • 【下载频次】326
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