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有机膦复合添加剂应用在碱法制备α-FeOOH过程中

Applying an Organic Phosphine Complex Additive to Preparing α-FeOOH by Alkaline Methods

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【作者】 古绪鹏陈同云吴鹏生

【Author】 GU Xu-Peng, CHEN Tong-Yun,WU Peng-Sheng (Chemical Departmeot of East China Institute of Metallurgy, Anhui Maanshan 243002, China)

【机构】 华东冶金学院化学工程系华东冶金学院化学工程系 安徽马鞍山 243002安徽马鞍山 243002安徽马鞍山 243002

【摘要】 合成了一种以有机磷化合物为主的复合添加剂,应用到碱法制备α-FeOOH过程中,发现反应的氧化速度有明显的提高、对α-FeOOH形貌有明显的影响.实验发现,在R=5.0时,复合添加剂用量为1.0×10-3g/L其晶形较佳.α-FeOOH经脱水、还原、氧化制得γ-Fe2O3磁粉其性能优良,主要指标完全达到高性能磁记录材料的要求.

【Abstract】 α-FeOOH was prepared by alkaline methods with an organic phosphine complex additive center. γ-Fe2O3 magnetic powders were made from α-FeOOH by releasing water, reducing, and oxidizing. It was found that the effects of the additives on the rate of oxidation and the topography of α-FeOOH are obvious. When the amount of the complex additive is 1.0×10-3g/L and R=5.0, magnetic-recording powders with high properties can be obtained.

  • 【文献出处】 无机材料学报 ,Journal of Inorganic Materials , 编辑部邮箱 ,2001年05期
  • 【分类号】TQ58
  • 【被引频次】14
  • 【下载频次】87
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