【摘要】 合成了一种新型的氯桥联三 (2 吡啶甲基 )胺 (TPA)双核铜配合物 { [(TPA)Cu(μ Cl) ]2 } (ClO4 ) 2 H2 O ,并通过X 射线衍射测得其晶体结构 .晶体属六方晶系 ,空间群为R 3,a =2 .8495 6 (18)nm ,b =2 .8495 6 (18)nm ,c =1.44 0 5 6 (14)nm ,α =90° ,β =90° ,γ =12 0°,V =10 .130 2 (13)nm3 ,Dx=1.5 2 2g·cm-3 ,z =3,F(0 0 0 ) =4719,R =0 .0 6 39,Rw=0 .15 0 8.更多还原

【Abstract】 A new binuclear Cu(Ⅱ) complex, {[(TPA)Cu(μ-Cl)] 2}(ClO 4) 2·H 2O,where TPA=tris(2-pyridylmethyl) amine, has been prepared and characterized by X-ray single crystal analysis. Crystal data: rhombohedral crystal system, R-3 space group, a=2.84956(18)nm,b= 2.84956(18)nm,c=1.44056(14)nm,α=90°,β=90°,γ=120°,V=10.1302(13)nm 3,D x=1.522g·cm -3,z=3,F(000)=4719,R=0.0639,R w=0.1508.更多还原