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含较高噪声重叠峰的分辨

Study of the Resolution of Overlapped Signals with Higher Noises

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【作者】 黄诚郑妍鹏莫金垣谢天尧

【Author】 HUANG Cheng, ZHENG Yan\|peng, MO Jin\|yuan, XIE Tian\|yao (School of Chemistry & Chemical Engineering, Zhongshan University, Guangdong Guangzhou 510275, China)

【机构】 中山大学化学与化工学院中山大学化学与化工学院 广东广州510275广东广州510275广东广州510275

【摘要】 采用Daubechies正交小波滤波和样条卷积分峰联用方法对信噪比S/N≥ 2的含噪重叠双峰进行滤噪和分峰处理。滤波部分采用阈值法 ,较详细地探讨了阈值的选取规则 ;分峰部分利用样条卷积法 ,并给出了其算法公式。处理速度较快 ,算法也较简单。通过对模拟和实验信号的处理 ,发现该联用方法很有效 ,处理后的峰的峰位置误差≤ 3 0 % ,峰面积误差≤ 3 0 %

【Abstract】 A coupled method of Daubechies Orthogonal Wavelet Filtration and Spline Convolution Resolution (SCR) is presented to process overlapped peaks with higher noises. The rules of selecting filtration threshold are discussed. And the algorithmic formula of SCR is given. Simulating signals of S/N(signal to noise ratio)≥2 are processed and the results meet the analytical request: The relative errors of peak intensity and peak area are less than 3 0% respectively. Besides the data from capillary electrophoresis are processed and the peaks with higher noises are separate successfully. The coupled method was programmed in MATLAB and its algorithm is simple. The sentences are less than 50 rows and the speed of processing data is also fast.

【基金】 国家自然科学基金 ( 2 9975 0 33) ;广东省自然科学基金 ( 980 340 )
  • 【文献出处】 计算机与应用化学 ,Computers and Applied Chemistry , 编辑部邮箱 ,2001年Z1期
  • 【分类号】O651
  • 【被引频次】2
  • 【下载频次】102
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