节点文献

大孔膦酸树脂吸附镱的研究

STUDIES ON THE ADSORPTION OF YTTERBIUM(Ⅲ) ON MACROPOROUS PHOSPHONIC ACID RESIN

  • 推荐 CAJ下载
  • PDF下载
  • 不支持迅雷等下载工具,请取消加速工具后下载。

【作者】 王永江; 熊春华; 舒增年; 沈秋仙;

【Author】 WANG Yong jiang 1,XIONG Chun hua 1,SU Zheng nian 1,SHENG Qiu xian 2 (1.Department of Chemistry,Lishui Teathers College,Lishui 323000,China; 2.Xikou campus,Lishui Teathers College,Lishui 323000,China)

【机构】 丽水师范专科学校化学系!浙江丽水323000; 丽水师范专科学校溪口校区!浙江丽水323000;

【Abstract】 In this paper the sorption behavior of Yb(Ⅲ) onto the macroporous phosphonic acid resin (MPAR) is reported.Experimental results show that the statically saturated sorption capacity is 328 mg/g·resin;Yb(Ⅲ) adsorbed on MPAR can be eluted by 1mol·L -1 HCl,elution percentage is 91.5%.The apparent rate constant is k 298 = 4.63×10 -5 s -1 .The sorption behavior of MPAR for Yb(Ⅲ) abides the Freundlich isotherm.The themodynamic parameter of sorption:enthalpy change ΔH for Yb(Ⅲ) is 50.4kJ·mol -1 .The coordination molar ratio of the functional group of MPAR to Yb(Ⅲ) is 3∶1.The bondforming conditions of MPAR for Yb(Ⅲ) is examined by IR spectrometry.

【关键词】 大孔膦酸树脂; 镱; 吸附;
【Key words】 macroporous phosphonic acid resin; Ytterbium; adsorption;
【基金】 浙江省教委资助项目 !(972 11);丽水市科委计划项目! (990 0 8)
  • 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2001年03期
  • 【分类号】O647.3
  • 【被引频次】13
  • 【下载频次】73
节点文献中: