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大孔膦酸树脂吸附镱的研究
STUDIES ON THE ADSORPTION OF YTTERBIUM(Ⅲ) ON MACROPOROUS PHOSPHONIC ACID RESIN
【Abstract】 In this paper the sorption behavior of Yb(Ⅲ) onto the macroporous phosphonic acid resin (MPAR) is reported.Experimental results show that the statically saturated sorption capacity is 328 mg/g·resin;Yb(Ⅲ) adsorbed on MPAR can be eluted by 1mol·L -1 HCl,elution percentage is 91.5%.The apparent rate constant is k 298 = 4.63×10 -5 s -1 .The sorption behavior of MPAR for Yb(Ⅲ) abides the Freundlich isotherm.The themodynamic parameter of sorption:enthalpy change ΔH for Yb(Ⅲ) is 50.4kJ·mol -1 .The coordination molar ratio of the functional group of MPAR to Yb(Ⅲ) is 3∶1.The bondforming conditions of MPAR for Yb(Ⅲ) is examined by IR spectrometry.
【基金】 浙江省教委资助项目 !(972 11);丽水市科委计划项目! (990 0 8)
- 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2001年03期
- 【分类号】O647.3
- 【被引频次】13
- 【下载频次】73