【摘要】 用微热量热法研究了用不同酸值的硫酸二乙酯作固化剂时 12 3树脂的固化过程 ,结果表明 ,酸值大于 1%的硫酸二乙酯对 12 3树脂的固化速率与固化反应深度有较大影响。当酸值小于1%时 ,固化的速率、深度和热效应基本不变。用FTIR研究了 12 3树脂的固化机理 ,发现随着固化反应的加深 ,16 5 1cm-1处的CC特征峰、3 0 95～ 3 0 75cm-1和 3 0 40～ 3 0 10cm-1处的CH2特征峰强度明显减弱 ,表明交联反应发生在单体的不饱和双键处。更多还原

【Abstract】 The curing process of 123 resin was studied by means of microcalorimetry with diethyl sulfate as a curing agent. The results show that the acid value(greater than 1 percent) of diethyl sulfate has an effect on the curing rate and cured degree. When acid values of diethyl sulfates vary in a proper range(less than 1 percent),curing rate,cured degree and curing heat of 123 resin will not be affected.The curing mechanism of 123 resin was studied through FTIR technique. It shows that with the deepening of cured degree,the magnitude of characteristic peaks of C [ZJ1Z,ZX;1Z,ZS;LX,Y] C [ZJ1Y,YS;1Y,YX] at 1 651 cm -1 、 CH 2 at 3 095～3 075 cm -1 and 3 040～3 010 cm -1 attenuates sharply,indicating that the cross link reaction takes place on the non saturated double bond within the C [ZJ1Z,ZX;1Z,ZS;LX,Y] C [ZJ1Y,YS;1Y,YX] group for monomers Ⅰ and Ⅱ.更多还原