【摘要】 在 2 92± 1K温度和 1 0 1× 10 5Pa压力下 ,以丙烷为参照物 ,采用相对速率方法测定了一系列醇与氯原子在气相中的反应速率常数 ,这些醇与氯的反应速率常数分别为 (单位 :10 7m3·mol-1·s-1) :甲醇k1=3 2 9,乙醇k2 =6 14,正丙醇k3=8 97,异丙醇k4 =4 0 0 ,正丁醇k5=11 7,异丁醇k6=12 5 ,叔丁醇k7=2 0 5 ,正戊醇k8=15 8,异戊醇k9=12 3更多还原

【Abstract】 The rate constants for reactions of chlorine atoms with a series of alcohols in gas\|phase have been measured at 292±1?K and \{1 01×10 5?Pa\} by a competitive technique. The alcohols include methanol( k 1 ), ethanol( k 2 ), n propanol( k 3 ), iso propanol( k 4 ), n butanol( k 5 ), iso butanol( k 6 ), tert butanol( k 7 ), n pentanol( k 8 ) and iso pentanol( k 9 ). The measured rate constants are k 1=3 29, k 2 =6 14, k 3 =8 97, k 4=4 00,k 5=11 7,k 6=12 5,k 7=2 05,k 8=15 8 , and k 9 =12 3, respectively (in units of 10 7?m 3·mol -1 ·s -1 ).更多还原