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拟除虫菊酯的分子设计与合成
The Design and Synthesis of New Pyrethroid Molecules
【摘要】 设计并制备了两种用作合成拟除虫菊酯的中间体—— α-甲基肉桂醇和溴代异丙叉丙酮 ,分别与第一菊酸酯化 ,得到两种新型的拟除虫菊酯。并经初步测试 ,这两种菊酯均具有较强的杀虫活性 ,且与天然除虫菊素相比 ,分子量减小 ,蒸气压升高 ,能在不加热的条件下自然挥发 ,增强药效
【Abstract】 Two kinds of intermediates for the synthesis of new pyrethroids--α methyl cinnamaldehyde and bromomesityl oxide--are designed and prepared in this paper. Esterification of the two compounds with chrysanthemum acid produces two kinds of new pyrethroids. Experiments show that the insecticidal effects of both new products are better than natural pyrethroids because their lighter molecular weight and higher vapor pressure can make them volatilized under natural conditions.
【关键词】 拟除虫菊酯;
α-甲基肉桂醇;
溴代异丙叉丙酮;
杀虫活性;
【Key words】 pyrethroid; α methyl cinnamaldehyde; bromomesityl oxide; insecticidal activity;
【Key words】 pyrethroid; α methyl cinnamaldehyde; bromomesityl oxide; insecticidal activity;
【基金】 国家自然科学基金资助项目;成都科技大学青年基金资助项目
- 【文献出处】 淮海工学院学报(自然科学版) ,JOURNAL OF HUAIHAI INSTITUTE OF TECHNOLOGY , 编辑部邮箱 ,2001年04期
- 【分类号】TQ450
- 【被引频次】3
- 【下载频次】280