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催化裂化油浆对渣油的改性机理

MECHANISM OF RESIDUUM MODIFICATION BY FCC SLURRY OIL

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【作者】 王延飞程健贾生盛沈本贤

【Author】 WANG Yanfei 1 ,CHENG Jian 2,JIA Shengsheng 2 and SHEN Benxian( 1Department of Chemical Engineering,Central-South Institute of Technology Hengyang 421001,Hunan,China; 2National Laboratory of Heavy oil Processing,Petroleum University of Ch

【机构】 南华大学化学工程系!湖南衡阳421001石油大学重油加工国家重点实验室!山东东营257062华东理工大学化工学院!上海200237

【Abstract】 acuum residuum is mixed with FCC slurry oil and the mechanism of residuum modification FCC slurry oil is studied.In the course of mixed residuum with FCC slurry oil,there are two competitive processes of solution and adsorption.The solution process means that some components with similar structure and solubility parameter from FCC slurry oil and residuum will dissolve in each other and small molecules will be freed from the surface of big molecules;The adsorption process means that asphaltene adsorbs molecules with polarity similar to and some molecules with similar surface structure adsorb on each other with small particles aggregating into big ones.The process of solution is balance with process of adsorption.When the ratio of FCC slurry oil is lower;while the process of adsorption predominates,when the ratio of FCC slurry oil is higher.The combination of the two competitive processes changes the composition and compatibility of residuum colloidal system,which leads to the decrease of solvent power and stability of residuum.The properties of mixed residuum that change with temperature should be further studied.

【关键词】 减压渣油催化裂化油浆胶体吸附
【Key words】 residuumFCC slurry oilcolloidadsorption
  • 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,2001年09期
  • 【分类号】TE624
  • 【被引频次】16
  • 【下载频次】214
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