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添加剂(Li2O BaO Na2O K2O)对 CaO基熔剂熔点影响的实验研究

Effect of additives(Li2O BaO Na2O K2O) on melting point of CaO-based fluxes

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【作者】 郭上型; 李桂荣; 董元篪; 陈二保; 张友平;

【Author】 GUO Shang- xing ,LI Gui- rong, DONG Yuan- chi ,CHEN Er- bao, ZHANG You- ping (Metallurgical Engineering Department of ECUM, Ma' anshan 243002,China)

【机构】 华东冶金学院冶金工程系!安徽马鞍山243002;

【摘要】 对于 CaO- SiO2- Fe2O3- MnO2- MgO- P2O5系熔剂,采用添加剂( Li2O BaO Na2O K2O)分别替代熔剂中部分 CaO,测定添加剂对实验熔剂熔点的影响关系。结果表明,添加剂的加入均具有降低熔剂熔点的效果,其熔点降低效果的强弱顺序为: Li2O>BaO>Na2O>K2O。在 w(添加剂 )≤ 25%范围内,随着加入量的增大, Li2O、 BaO使熔剂熔点不断降低,而添加 Na2O、 K2O的熔剂熔点发生异常变化。根据实验结果,推荐 Li2O作为 CaO基熔剂的添加剂。当熔剂中: w( CaO+ Li2O) /w( SiO2)≤ 2.5, w( Li2O)≥ 5%, w( Fe2O3)≥ 5%时,熔剂熔点≤ 1 384℃。

【Abstract】 Effect of additives(Li2O, BaO, Na2O, K2O) on melting point of CaO- based fluxes have been studied .The results indicate that the ability of additives to lower melting point of the fluxes decreased in the following order: Li2O>BaO>Na2O>K2O.The melting point of the fluxes lowered with Li2O, BaO instead of CaO in the CaO- based fluxes. It is also found that unusual changes of the melting point in the fluxes have taken place with Na2O, K2O instead of CaO in the CaO- based fluxes. According to the experimental result, using Li2O as additives of the CaO- based fluxes is recommended. By controlling the flux composition to w(CaO+ Li2O)/w(SiO2)≤ 2.5,w(Li2O)≥ 5%, and w(Fe2O3)≥ 5% , the melting point of the fluxes is less than 1 384℃ .

【关键词】 添加剂; 熔点; CaO基熔剂;
【Key words】 additives; melting point; CaO- based flud;
【基金】 国家自然科学基金项目!( 59774015)
  • 【文献出处】 安徽工业大学学报 ,Journal of East China University of Metallargy , 编辑部邮箱 ,2001年01期
  • 【分类号】TF70
  • 【被引频次】8
  • 【下载频次】112
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