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脱氢枞胺键合交联聚苯乙烯树脂的制备

Preparation and Characterization of Covalently Bonded Dehydroabietylamine Derivatized Cross-linked Polystyrene

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【作者】 何曼沈德渊

【Author】 HE Man, SHEN De yuan (School of Chemistry and Chemical Technology, Southeast University, Nanjing 210096, China; Research Center of Physical and Chemical Analysis, Nanjing Forest University, Nanjing 210028, China)

【机构】 东南大学化学化工系!南京210096南京林业大学理化中心!南京210028

【摘要】 运用高分子反应法 ,制备脱氢枞胺键合交联聚苯乙烯树脂。反应分三步进行 :醚化反应、双键环氧化和脱氢枞胺与环氧基开环反应。探讨了每一步合成的最佳工艺条件。通过红外光谱对该功能高分子进行了结构表征。并对该合成产物进行对映体分离的初步应用

【Abstract】 To produce covalently bonded dehydroabietylamine derivatized cross linked polystyrene by macromolecular reaction. The synthetic method involves three steps. The first step is synthesis of ethers and the second step is epoxidation of double bonds. The third step is reaction of dehydroabietylamine with epoxy group. The optimum technological conditions of each step were discussed. The functional macromolecular were characterized by IR. And the product was tried to resolute enantiomers.

  • 【文献出处】 功能高分子学报 ,Journal of Functional Polymers , 编辑部邮箱 ,2001年03期
  • 【分类号】O632
  • 【被引频次】4
  • 【下载频次】114
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