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聚丙烯接枝马来酸酐/SiO2复合载体型钛催化剂制备及表征
PREPARATION AND CHARACTERIZATION OF POLYMPROPYLENE GRAFTING MALEIC ANHYDRIDE/SiO2 COMPOSITE-SUPPORTED TITANIUM CATALYSTS
【Abstract】 The composite,prepared with polypropylene grafting maleic anhydride and silica crosslinked by 3 aminopropyltriethyoxysilane,was used as the carrier to support titanium chloride.XPS and FTIR measurements were emplyed to investigate the states of several atoms during stepwise supporting catalyst for clarifying the mechanism.The results showed two possible mechanisms of active catalytic sites on the composite carrier:the catalytic sites bridged through MAO on the inorganic silica gel;on contrary,the catalytic sites bridging with carbonyls of amide formed in the composite.
【关键词】 聚丙烯接枝马来酸酐;
复合载体;
TiCl;
【Key words】 Polypropylene grafting maleic anhydride; Composite support; Titanium;
【Key words】 Polypropylene grafting maleic anhydride; Composite support; Titanium;
【基金】 中国科学院重大知识创新基金 (KGCX2 0 3 2 );“百人计划”专项基金资助项目
- 【文献出处】 高分子学报 ,Acta Polymerica Sinica , 编辑部邮箱 ,2001年06期
- 【分类号】O643.3
- 【被引频次】10
- 【下载频次】150