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聚丙烯接枝马来酸酐/SiO2复合载体型钛催化剂制备及表征

PREPARATION AND CHARACTERIZATION OF POLYMPROPYLENE GRAFTING MALEIC ANHYDRIDE/SiO2 COMPOSITE-SUPPORTED TITANIUM CATALYSTS

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【作者】 朱宁孙文华李子龙邵长星胡友良

【Author】 ZHU Ning, SUN Wenhua, LI Zilong, SHAO Changxing, HU Youliang (State Key Laboratory of Engineering Plastics, Center for Molecular Sicence, Institute of Chemistry, Chinese Academy of Sciences, Beijing\ 100080)

【机构】 中国科学院化学研究所分子科学中心工程塑料国家重点实验室中国科学院化学研究所分子科学中心工?

【Abstract】 The composite,prepared with polypropylene grafting maleic anhydride and silica crosslinked by 3 aminopropyltriethyoxysilane,was used as the carrier to support titanium chloride.XPS and FTIR measurements were emplyed to investigate the states of several atoms during stepwise supporting catalyst for clarifying the mechanism.The results showed two possible mechanisms of active catalytic sites on the composite carrier:the catalytic sites bridged through MAO on the inorganic silica gel;on contrary,the catalytic sites bridging with carbonyls of amide formed in the composite.

【基金】 中国科学院重大知识创新基金 (KGCX2 0 3 2 );“百人计划”专项基金资助项目
  • 【文献出处】 高分子学报 ,Acta Polymerica Sinica , 编辑部邮箱 ,2001年06期
  • 【分类号】O643.3
  • 【被引频次】10
  • 【下载频次】150
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