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时效对无铅焊料Ni-P/Cu焊点的影响

EFFECT OF AGING ON THE MICROSTRUCTURE AND SHEAR STRENGTH OF LEAD FREE/Ni-P/Cu SOLDER JOINTS

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【作者】 肖克来提杜黎光盛玫罗乐

【Author】 SHAWKRET Ahat, DU Liguang, SHENG Mei, LUO Le (Shanghai Institute of Metallurgy, The Chinese Academy of Sciences, Shanghai 200050)

【机构】 中国科学院上海冶金研究所中国科学院上海冶金研究所!研究员 上海市200050

【摘要】 研究了150℃等温时效对62Sn36Pb2Ag/Ni-P/Cu及共晶SnAg/Ni-P/Cu表面贴装焊点微结构及剪切强度的影响.结果表明,在钎料与Ni-P间的界面存在Ni3Sn4金属间化合物层,其厚度随时效时间增加,Ni-P层的厚度减小;时效后,SnPbAg、SnAg焊点的剪切强度下降.对于SnAg焊点,时效250h后其剪切强度剧烈下降,断裂发生在Ni-P/Cu界面上,在长时间时效后焊点一侧的Ni-P层中P的含量较高可能是Ni-P/Cu结合强度变差的主要原因.SnPbAg焊点保持着较高的剪切强度.

【Abstract】 The effect of aging on the microstructure and shear strength of 62Sn36Pb2Ag/NiP/Cu and SnAg/Ni-P/Cu surface mount solder joints was investigated. Intermetallic (IMC) layer of Ni3Sn4 was found in the interface between both solders and Ni-P layer and it thickens with aging time, meanwhile accompanied with a decrease of the thickness of remaining Ni-P layer. A drastic drop of the shear strength of SnAg solder joint happens after 250h aging and fracture was found to occur at the interface between Ni-P layer and Cu substrate. This may possibly be caused by the rapid accumulation of P in the remaining Ni-P layer. which results in a poor adhesion between Ni-P and Cu substrate. On the other hand, SnPbAg solder joint keeps a relatively higher value of shear strength even though it decreases with aging time.

【关键词】 SnPbAgSnAg焊点时效微结构剪切强度
【Key words】 SnPbAg and SnAg soldersagingmicrostructureshear strength
  • 【文献出处】 材料研究学报 ,Chinese Journal of Material Research , 编辑部邮箱 ,2001年02期
  • 【分类号】TG407
  • 【被引频次】10
  • 【下载频次】145
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