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有机溶剂热生长晶体及其应用

SOLVO-THERMAL SYNTHESIS OF METAL CHALCOGENIDES AND ITS EMPLOYMENT

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【作者】 陈震郑曦陈日耀程蔚张义康

【Author】 CHEN Zhen, ZHENG Xi, CHEN Riyao, CHENG Wei (Experiment Center, Fujian Normal University, Fuzhou 350007) ZHANG Yikang (Shandong Linyi Education College)

【机构】 福建师范大学实验中心!福州市350007福建师范大学山东临沂教育学院

【摘要】 介绍了有机溶剂热生长技术在金属碲、硒多聚物合成中的应用,并讨论了这类化合物的结构特征,及其在制备纳米级半导体薄膜、催化剂载体和离子交换材料方面的应用前景

【Abstract】 Solvo-thermal syntheses of metal chalcogenides have been overviewed. All three elements of S, Se and Te, have a tendency to catenate. This results not only in rings or chains of their several elemental forms, but also in the polychalcogenide Qn2-(Q=S, Se, Te, n=2-6) ions that can exist in solutions or in the solid-state in various sizes. Organic solvent is easy to reaction with precursor of transition metal to produce a complex canon in the solvo-thermal synthesis of metal chalcogenides. The technique can be employed in preparing a semiconductor film and using to prepare the catalyze carrier materials and relevant to many inportant processes, such as hydrodesulfurization of crude oil, hydrogenation of unsaturated and aromatic hydrocarbons, biosynthasis of metalloproteins, and even the hydrothermal conversion of metals to their binary chalcogenide minerals in nature.

【基金】 福建省自然科学基金资助项目A9910009
  • 【文献出处】 材料研究学报 ,Chinese Journal of Material Research , 编辑部邮箱 ,2001年02期
  • 【分类号】O78
  • 【被引频次】32
  • 【下载频次】339
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