节点文献
二氯(2,6-二甲基吡啶)铜(Ⅱ)配合物的合成及晶体结构(英文)
Synthesis and Crystal Structure of Dichloro(2,6-dimethylpyridine ) Copper(Ⅱ) [ Cu (C7H9N )2] Cl2
【摘要】 在DMF溶剂中,CuCl2与2,6-二甲基吡啶反应合成并培养了二氯(2,6-二甲基吡啶)铜(Ⅱ)配合物的单晶,通过X-射线衍射分析测定了分子结构。单晶在三斜晶体系中收集,空间群P-1的晶胞参数为a=7.6718(15),b=8.0352(16),c=8.0819(16)A,a=117.08(3),β=113.20(3),γ=93.91(3)°,Z=2.单晶结构中,Cu(Ⅱ)与两个氮原子和两个氯离子相连。
【Abstract】 The complex [Cu (C7H9N)2] Cl2was prepared by reaction of CuCl2 with 2, 6 dimethylpuridine in DMF. It has been determined by single crystal X-ray analyses. The crystals are triclinic, space guoup P-1, with a=7. 6718(15), b=8. 0352(16), c=8. 0819 (16) A, a= 117. 08(3), β= 113. 20(3), γ = 93. 91 (3)°, and Z=2. The complex is monomeric, with the Cuatom coordinated to two N atoms and two Cl-ions. The compound displays simple paramagnetic behaviour.
【关键词】 二氯(2,6-二甲基吡啶)铜(Ⅱ);
配合物;
晶体结构;
铜(Ⅱ);
【Key words】 Dichloro(2, 6- dimethylpyridine) copper(Ⅱ); Complexes; Crystal structure; Copper (Ⅱ);
【Key words】 Dichloro(2, 6- dimethylpyridine) copper(Ⅱ); Complexes; Crystal structure; Copper (Ⅱ);
- 【文献出处】 青岛化工学院学报(自然科学版) ,JOURNAL OF QINGDAO INSTITUTE OF CHEMICAL TECHNOLOGY , 编辑部邮箱 ,2000年04期
- 【分类号】O627
- 【下载频次】74