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硬软酸碱理论与两可亲核性
RELATIONSHIP BETWEEN HARD-SOFT ACID-BASE THEORY AND DINUCLEOPHILICITY
【摘要】 从硬软酸碱理论出发对两可试剂的亲核性,取代反应中催化剂的选择性进行了综合的解释,指出了多官能团亲电反应中心,通过实例证明了离子型反应的选择性规律.
【Abstract】 The synthetic explanation of nucleophiticity of diagent and catalyst selection in substitution reaction is discussed according to hard-soft acid-base theory Electrphitic reaction center of multifunctional group is determined. The rule of selection in ionic reaction is proved through experimental examples.
【关键词】 硬软酸碱;
亲核性;
反应中心;
选择;
【Key words】 hard-soft acid-base; nucleophiticity; reaction center; selection;
【Key words】 hard-soft acid-base; nucleophiticity; reaction center; selection;
- 【文献出处】 佳木斯大学学报(自然科学版) ,JOURNAL OF JIAMUSI UNIVERSITY(NATURAL SCIENCE EDITION) , 编辑部邮箱 ,2000年02期
- 【分类号】O621
- 【被引频次】1
- 【下载频次】232