【摘要】 以三种烯丙醇为起始原料 ,经溴代生成烯丙基溴 ,然后与无水苯亚磺酸钠发生亲核取代反应生成烯丙基砜。烯丙基溴与烯丙基砜在相转移催化下的偶联反应也可合成新的烯丙基砜。作者用这两种方法合成了六种烯丙基砜。初步探讨了反应温度 ,催化剂等对反应的影响。产物结构经IR ,1 HNMR等波谱分析确证。更多还原

【Abstract】 This paper reported the synthesis of six allylic sulfones through the bromination of three allylic aclohol,the sulfonylation of allylic bromide,and the coupled reaction between allylic bromides and allylic sulfones.All products were characterized by IR, 1HNMR.更多还原