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微波辐射技术在聚乙烯醇降解反应中的应用

POLYVINYL ALCOHOL DEGRADATION UNDER MICROWAVE IRRADIATION

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【作者】 夏立新李坤兰庞军曹国英奚祖威

【Author】 Xia Lixin Li kunlan Pang Jun Cao Guoying Xi Zuwei(Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023)

【机构】 中国科学院大连化学物理研究所!大连116023

【摘要】 考察了微波功率、pH值、H2O2用量和反应时间对聚乙烯醇降解反应的影响.实验表明,在微波辐射条件下,微波功率为800W,辐射时间为1min,pH值为3,H2O2用量为依22gH2O2·100g-1PVA时,5ml聚乙烯醇(7%)的平均聚合度能够在1min内降至67.与常规油浴加热相比,反应速度提高10—20倍.

【Abstract】 Under microwave irradiation the effect of microwave power, pH, H2O2 amount and reaction time on polyvinyl alcohol (PVA) degradation has been investigated in this paper. It was found that 5ml 7% PVA degree of polymerization (DP) was quickly degraded to 67 under microwave power 800W, ph = 3, 22g H202·100g-1 PVA in 1min. Compared with conventional oil-bath heating, the degradation rate of PVA is accelerated 10-20 times under microwave irradiation.

【关键词】 微波辐射聚乙烯醇降解
【Key words】 microwave irradiationpolyvinyl alcoholdegradation.
  • 【文献出处】 环境化学 ,Environmental Chemistry , 编辑部邮箱 ,2000年06期
  • 【分类号】X17
  • 【被引频次】42
  • 【下载频次】291
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