【摘要】 以二苯基二氯化锡和炔 (烯 )基膦酸盐为原料 ,在乙醇中反应 ,合成了 8种新的二苯基锡不饱和烃基膦酸酯 Ph2 Sn O2 P(O) R(R=C CC3H7- n,C CC4H9- n,C CC5H1 1 - n,C CC6H1 3- n,C CCH2 OCH3,C CCH2 OC2 H5,C CPh,CH CCl Ph) ,利用元素分析、IR,1 H NMR和 TG- DAT对其组成和结构进行了表征。更多还原

【Abstract】 Eight new diphenyltin alkynyl or alkenyl phosphates with formular Ph₂SnO₂P（O）R（R=[KG-2]C[ZJSX,Y] CC₃H₇.n [KG-2],[KG-2]C[ZJSX,Y] CC₄H₉.n [KG-2],[KG-2]C[ZJSX,Y] CC₅H 11 .n [KG-2],[KG-2]C[ZJSX,Y] CC₆H 13 .n [KG-2],[KG-2]C[ZJSX,Y] CCH₂OCH₃ [KG-2],[KG-2]C[ZJSX,Y] CCH₂OC₂H₅ [KG-2],C[ZJSX,Y] CCPh [KG-2],[KG-2]C[ZJLX,Y] CClPh [KG-2]）were synthesized by the reaction of diphenyltin dichloride and alkynyl or alkenyl phosphates in absolute ethyl alcohol. Their structures were characterized through elemental analysis, IR, 1H NMR and TG.DTA. [KH-2]更多还原