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氧化石墨的合成及其结构研究

Research on the Synthesis and Structure of Graphite Oxide

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【作者】 苏育志刘成波张瑞芬褶艳芬

【Author】 SU Yu-zhi; LIU Cheng-bo; ZHANG Rui-fen; XIAN Yan-fen (. Dept. of Chemistry, Guangzhou Normal University, Guangzhou 510405, China Institute of Envionment-Protect of Foshan,Guangdong 528042, China)

【机构】 广州师范学院化学系!广东广州510405佛山市环境保护研究所!广东佛山528042

【摘要】 在Hummer法的基础上合成了氧化石墨,对氧化石墨的组成、分子结构及其还原性进行了测试与分析,结果表明,氧化石墨结构中含有大量的极性基团,这些基团的存在赋予了氧化石墨在极性溶剂中有良好的溶剂化能力。

【Abstract】 Graphite oxide was synthesized from natural graphite powder by graphite oxidation with KMnO4 in concentrated H2SO4 according to Hummers method. The component and structure of graphite oxide were investigated in detail, had on the results of IR, XRD, TG and DSC measurements. The results shows that graphite oxide possesses hydroxyl, carbonyl and other groups between the graphite Oxide lamellae. Due to the presence of these polar groups, various kinds of polar molecules and polar polymer can be inserted into the lamellae to form different kinds of intercalated graphite oxide nanocomposites.

  • 【文献出处】 广州师院学报(自然科学版) ,JOURNAL OF GUANGZHOU NORMAL UNIVERSITY , 编辑部邮箱 ,2000年03期
  • 【分类号】TB383
  • 【被引频次】39
  • 【下载频次】1552
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