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丙烯酰胺及丙烯酸反相微乳液聚合体系电导行为

Conductive behavior of the inverse microemulsions containing acrylamide and/or acrylic acid

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【作者】 李晓刘戈袁惠根张卫英

【Author】 LI Xiao 1, LIU Ge 2, YUAN Hui-gen 2, ZHANG Wei-ying 1 ( 1. Department of Chemical Engineering , Fuzhou University, Fuzhou, Fujian 350002, China; 2. Institute of Polymer Science and Engineering , Zhejiang University, Hangzhou, Zhejiang 3100

【机构】 福州大学化学工程系!福建福州350002浙江大学高分子科学与工程研究所!浙江杭州310027

【摘要】 以Span80 -Tween60复合作为乳化剂 ,研究复合乳化体系的HLB值对丙烯酰胺及丙烯酸反相微乳液电导行为的影响 .结果表明随着水相分率的提高 ,体系电导率经历突变从油相电导趋向于水相电导 ,而且水相单体浓度越高 ,出现电导率突变的水相分率越低 .确定了Span80 -Tween60复合稳定的煤油 -水 -丙烯酰胺 (丙烯酸 )反相微乳液体系 ,HLB值以 7.4 8左右为佳 .

【Abstract】 The influence of HLB values from Span80-Tween60 on the conductive behavior of inverse microemulsions containing acrylamide and/or acrylic acid has been investigated. The sharp increase of conductivity was observed when aqueous phase fraction was increased to some extent. The higher acrylamid concentration was in aqueous phase, the lower the aqueous phase fraction was for sharp conductivity increase. It was also found that the value of HLB around 7.48 was the optimum for preparing kerosine-water-AM(AA) inverse microemulsion, where the amount of emulsifier required was minimum and the aqueous phase fraction before sharp increase of conductivity was relatively higher.

【基金】 化学工程国家重点联合实验室浙江大学聚合反应工程实验室开放基金资助项目!(KF9904)
  • 【文献出处】 福州大学学报(自然科学版) ,JOURNAL OF FUZHOU UNIVERSITY(NATURAL SCIENCES EDTION) , 编辑部邮箱 ,2000年04期
  • 【分类号】O623.73
  • 【被引频次】18
  • 【下载频次】211
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