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固体超强酸TiO2/SO42-催化合成羟基乙酸酯

Synthesizing glycolic acid esters using TiO2/SO42- solid super acid as a catalyst

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【作者】 张竞清陈国导

【Author】 ZHANG Jing qing, CHEN Guo dao (Sciences School, Foshan University, Foshan 528000, China)

【机构】 佛山科学技术学院理学院!广东佛山528000

【摘要】 本文用固体超强酸 Ti O2 /SO42 -催化合成了羟基乙酸酯。反应时间为 4 h,产物纯化简单 ,其中几个酯得到收率达 83 %以上

【Abstract】 This paper concerned in the synthesizing of glycolic acid esters with alcohol. and glycolic acid by solid super acid TiO 2/SO 4 2- as catalysts. The specifications of the appropriate condition were obtained from the experiments. When the acid/alcohol mole ratio was 0.07∶0.140; catalyst 1.5 g and the reaction time 4hrs, the yield of propyl Hydrosyacetate could amount to 86.5%. The other glycolic acid esters were also synthesized by using TiO 2/SO 4 2- as catalyst.

  • 【文献出处】 佛山科学技术学院学报(自然科学版) ,JOURNAL OF FOSHAN UNIVERSITY(NATURAL SCIENCE EDITION) , 编辑部邮箱 ,2000年02期
  • 【分类号】O643
  • 【被引频次】2
  • 【下载频次】79
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