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微波加热条件下ZnNi/HZSM-5催化剂上烷烃的芳构化反应
Aromatization of Light Hydrocarbon over ZnNi/HZSM-5 Catalyst under Microwave Heating
【Abstract】 The aromatization of n hexane and mixed C 4 hydrocarbon was investigated under microwave heating over ZnNi/HZSM 5 catalyst of lower activity in order to compare with that under the conventional heating. For the n hexane aromatization, the selectivity for benzene and toluene by the microwave heating at 450 ℃ increases by 4% and 5%, respectively, and the aromatics yield by the microwave heating at 480℃ increases by 4% , compared with those by the conventional heating. For the mixed C 4 olefine aromatization, the BTX yield by the microwave heating at 400 ℃ increases by 17 08% and the aromatics selectivity is also higher than that by the conventional heating.
【关键词】 微波辐射;
正己烷;
混合丁烯;
芳构化;
锌;
镍;
HZSM5分子筛;
【Key words】 microwave irradiation; n hexane; mixed C 4 hydrocarbon; aromatization; zinc; nickel; HZSM 5 zeolite;
【Key words】 microwave irradiation; n hexane; mixed C 4 hydrocarbon; aromatization; zinc; nickel; HZSM 5 zeolite;
【基金】 国家自然科学基金!(2 976 0 0 8)
- 【文献出处】 催化学报 ,Chinese Journal of Catalysis , 编辑部邮箱 ,2000年05期
- 【分类号】O643
- 【被引频次】12
- 【下载频次】104