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微波加热条件下ZnNi/HZSM-5催化剂上烷烃的芳构化反应

Aromatization of Light Hydrocarbon over ZnNi/HZSM-5 Catalyst under Microwave Heating

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【作者】 高昌录张金生孙兆林刘宁宁程志林桂建舟

【Author】 GAO Changlu, ZHANG Jinsheng, SUN Zhaolin, LIU Ningning, CHENG Zhilin, GUI Jianzhou (Department of Applied Chemistry, Fushun Petroleum Institute, Fushun 113001, China)

【机构】 抚顺石油学院应用化学系!抚顺113001

【Abstract】 The aromatization of n hexane and mixed C 4 hydrocarbon was investigated under microwave heating over ZnNi/HZSM 5 catalyst of lower activity in order to compare with that under the conventional heating. For the n hexane aromatization, the selectivity for benzene and toluene by the microwave heating at 450 ℃ increases by 4% and 5%, respectively, and the aromatics yield by the microwave heating at 480℃ increases by 4% , compared with those by the conventional heating. For the mixed C 4 olefine aromatization, the BTX yield by the microwave heating at 400 ℃ increases by 17 08% and the aromatics selectivity is also higher than that by the conventional heating.

【基金】 国家自然科学基金!(2 976 0 0 8)
  • 【文献出处】 催化学报 ,Chinese Journal of Catalysis , 编辑部邮箱 ,2000年05期
  • 【分类号】O643
  • 【被引频次】12
  • 【下载频次】104
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