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邻二甲苯选择氧化的V-Ti-O复合氧化物超细微粒催化剂

The Composite V Ti O Ultrafine Particle Catalyst for Selective Oxidation of o Xylene

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【作者】 刘浏林明刘持标范以宁颜其洁陈懿

【Author】 LIU Liu, LIN Ming, LIU Chibiao, FAN Yining, YAN Qijie, CHEN Yi (Department of Chemistry, Nanjing University, Nanjing 210093, China)

【机构】 南京大学化学系!南京210093

【Abstract】 The structure and catalytic properties of V Ti O ultrafine particle catalyst for selective oxidation of o xylene have been studied. TEM and XRD results show that the particle size is in the range of 20~40 nm, and vanadium oxide is highly dispersed in TiO 2 (anatase). The catalytic activity of the V Ti O ultrafine particle catalyst for selective oxidation of o xylene to phthalic anhydride(PA) is higher than that of the larger oxide particles with the same catalyst composition prepared by impregnation and coprecipitation methods, indicating that the ultrafine V Ti O oxide particles are potentially new catalytic materials for the selective oxidation of o xylene to phthalic anhydride.

【基金】 国家自然科学基金!(29503018);国家自然科学基金!重大项目(G597005);中国博士后基金
  • 【文献出处】 催化学报 ,CHINESE JOURNAL OF CATALYSIS , 编辑部邮箱 ,2000年01期
  • 【分类号】O643.36
  • 【被引频次】1
  • 【下载频次】87
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