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邻二甲苯选择氧化的V-Ti-O复合氧化物超细微粒催化剂
The Composite V Ti O Ultrafine Particle Catalyst for Selective Oxidation of o Xylene
【Abstract】 The structure and catalytic properties of V Ti O ultrafine particle catalyst for selective oxidation of o xylene have been studied. TEM and XRD results show that the particle size is in the range of 20~40 nm, and vanadium oxide is highly dispersed in TiO 2 (anatase). The catalytic activity of the V Ti O ultrafine particle catalyst for selective oxidation of o xylene to phthalic anhydride(PA) is higher than that of the larger oxide particles with the same catalyst composition prepared by impregnation and coprecipitation methods, indicating that the ultrafine V Ti O oxide particles are potentially new catalytic materials for the selective oxidation of o xylene to phthalic anhydride.
【关键词】 邻二甲苯;
选择氧化;
氧化钒;
氧化钛;
复合氧化物催化剂;
超细微粒;
【Key words】 o xylene; selective oxidation; vanadium pentoxide; titania; composite oxide catalyst; ultrafine particle;
【Key words】 o xylene; selective oxidation; vanadium pentoxide; titania; composite oxide catalyst; ultrafine particle;
【基金】 国家自然科学基金!(29503018);国家自然科学基金!重大项目(G597005);中国博士后基金
- 【文献出处】 催化学报 ,CHINESE JOURNAL OF CATALYSIS , 编辑部邮箱 ,2000年01期
- 【分类号】O643.36
- 【被引频次】1
- 【下载频次】87