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有机添加剂对模拟油EACN值及动态界面张力的影响

THE EFFECTS OF ORGANIC SURFACTANTS ON EACN VALUE AND TRANSIENT INTERFACIAL TENSION OF MODELLING OIL

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【作者】 张路; 赵濉; 徐欣炜; 罗澜; 陈咏梅; 俞稼镛;

【Author】 ZHANG Lu, ZHAO Sui, XU Xin Wei, LUO Lan, CHEN Yong Mei, YU Jia Yong(Inst of Photographic Chemistry, Academia Sinica, Beijing 100101, China)

【机构】 中国科学院感光化学研究所!北京100101;

【摘要】 本文通过改变两种石油磺酸盐的混合比例,配制出碳数最低值不同的一系列混合表面活性剂溶液作为标尺,考察了几种有机酸、十八醇、Span60 及两种卟啉( OEP和ETIO) 对正癸烷模拟油的EACN 值及油水界面张力的影响。

【Abstract】 A series of standard aqueuos solutions of petroleum sulfonates LH and La in various proportions with salinity 0.171 mol/L NaCl is used as the aqueous phase and different normal alkanes(C 5-C 14 ,C 10 in most cases)-as the oil phase modelling the crude oil in EOR studies. Some saturated aliphatic mormal acids(C 8,C 10 ,C 12 ,C 18 ), oleic acid, cyclohexyl carboxylic acid, and two porphyrins(OEP and ETIO) are added into the alkanes and their EACN values are determined using the criteria rules as minimum ACN value for the standard aqueous phase which gives the lowest stable value of transient interfacial tension with the alkane. The transient interfacial tension is also studied. The results obtained are discussed and reasoned.

【基金】 国家攀登(B) 计划“复合驱强化采油技术中重大基础性研究”项目!( 项目编号8533) 资助
  • 【文献出处】 油田化学 ,OILFIELD CHEMISTRY , 编辑部邮箱 ,1999年04期
  • 【分类号】TE39
  • 【被引频次】15
  • 【下载频次】168
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