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六氯苯的激光溅射合成

Synthesis from tetrachloromethane to hexachlorobenzene by laser ablation

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【作者】 周异男阎福林祝振富

【Author】 ZHOU Yi-Nan; YAN Fu-Lin; ZHU Zhen-Fu(Department of Basic Courses, Xinxiang Medical College, Xinxiang,453003)

【机构】 新乡医学院化学教研室!河南新乡453003

【摘要】 目的寻找合成全氯代芳香烃的新方法。方法用激光溅射多相反应体系,以石墨为固体靶,以四氯化碳为气相和液相反应物,通过等离子体反应进行合成。结果从合成产物中分离表征了六氯苯。结论将激光溅射这一物理方法与化学合成的反应条件相结合,是一种化学合成的新方法。

【Abstract】 Objective In order to search a new methed of chemical synthesis, we attempted to synthesize the perchlorinated aromatic hydrocarbon by plasma reaction. Metheds By laser ablating a heteroge-neous reaction system which was consisted of solid graphite, liquid and gaseous tetrachloromethane, synthesis was carried out by plasma reaction. Results Hexachlorobenzene was synthesized, separated and characterized Conclusion Laser ablation as a physical method can be combined with conditions of chemical building-up reactions, which is a new chemical synthesis method.

  • 【文献出处】 新乡医学院学报 ,JOURNAL OF XINXIANG MEDICAL COLLEGE , 编辑部邮箱 ,1999年03期
  • 【分类号】TQ463.4
  • 【下载频次】39
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