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二氧化钒薄膜在α-Al2O3衬底上的外延生长及其金属-半导体相变特性研究
Epitaxial Growth and Phase Transition Properties of Vanadium DioxideThin Film on Sapphire Substrate
【摘要】 利用XRD及XRD极图技术表征了用激光剥离技术生长的VO2薄膜.结果表明:在衬底温度为500,氧气偏压6.67Pa的条件下,在Al2O3(1120)衬底上能实现VO2的二维外延生长.薄膜的结构除了与沉积工艺有关外,还和衬底的取向密切相关.在Al2O3(1120)衬底上,定向生长的(100)VO2在Millar指数<5时,除了[010]以外,不存在其他晶格矢量与衬底相匹配,从而不可能实现三维单晶薄膜的外延生长.电学特性的测试结果显示,在温度为65左右,VO2薄膜出现相交,薄膜的电阻率变化达4个数量级.
【Abstract】 Vanadium Dioxide(VO2) thin films deposited on(1120) sapphire substrates by pulsed laser ablation were characterized by using the techniques of XRD , XRD pole figure, RBS/channeling andelectrical measurements The results show that VO2 thin film on the (1120) sapphire grows pi-taxially with out of -plane:(100)VO2/ /(1120)sapphire and in-plane:VO2[010]/ /sapphire[0001].Channeling cannot be found in RBS/Channeling analysis ,indicating that the film fails to singlecrystalline growth .The further analysis of the crystallography of the (100)VO2 reveals that within 5 lattice periods,no other lattice vector exists in the (100)plane of Vo2 to match the latticeof sapphire,therefore,it is impossible to deposit single crystal thin film on (1120)sapphireas observed in the study .During the phase transition,the electrical resistivity changes aboutfour orders.
- 【文献出处】 无机材料学报 ,JOURNAL OF INORGANIC MATERIALS , 编辑部邮箱 ,1999年05期
- 【分类号】TN304.055
- 【被引频次】20
- 【下载频次】256