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“推-拉”型偶氮苯化合物的质谱分析
Analysis of Mass Spectra of Azobenzene Compoundswith ″ Push - Pull″ Structure
【摘要】 “推- 拉”型偶氮苯化合物分子的共振结构决定了其关键碎裂方式, 有内氢键作用时偶氮则附着于给电子端, 而后续的碎裂过程则遵循各自主要官能团的裂解规律。
【Abstract】 A series of azobenzene compounds with″ push-pull″ structure have been studied by analyzing the EI mass spectra. The results show that main fragmentation pattern of the compounds was governed by their resonant structure. Azo group will adhere to the group which donated electron, when an internal hydrogen bond is presented in the molecule of the compounds, and succeeding fragmentation pattern is determined by presenting main functional group.
【基金】 广东省自然科学基金!资助项目(97151)
- 【文献出处】 分析测试学报 ,JOURNAL OF INSTRUMENTAL ANALYSIS , 编辑部邮箱 ,1999年06期
- 【分类号】O657.63
- 【下载频次】71