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甲基二氯硅烷—甲苯等压汽液平衡研究
STUDY ON ISOBARIC VAPOR-LIQUID EQUILIBRIUM FOR METHYLDICHLOROSILANE-TOLUENE BINARY SYSTEM
【摘要】 用泵式沸点仪测定了甲基二氯硅烷—甲苯二元系在常压下的汽液平衡数据,并用间接法由TPX 推算了与之平衡的汽相组成,用最小二乘法求出了该系统的液相活度系数模型参数,由模型参数推算的泡点温度与实验值符合良好,所得数据通过了热力学一致性检验。
【Abstract】 This paper describes the measurement of the vapor-liquid equid equilibrium (VLE) data of methyldichlorosilane-toluenene binary system at 101.3 kPa with a new pump-ebulliometer.The equilibrium composition of the vapor phase had been calculated from TPX by indirect method.The model parameters of liquid activity coefficient were correlated by the least square method.The calculated boiling points were in good agreement with the experimental data.
【基金】 江西省自然科学基金
- 【文献出处】 南昌大学学报(理科版) ,JOURNAL OF NANCHANG UNIVERSITY(NATURAL SCIENCE) , 编辑部邮箱 ,1999年04期
- 【分类号】O623.1
- 【被引频次】2
- 【下载频次】44