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溴代Ⅱ型苯并三唑类紫外线吸收剂的合成

THE SYNTHESIS OF TYPE Ⅱ UV ABSORBERS OF BROMINATED BENZOTRIAZOL STRUCTURE

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【作者】 祁国珍; 王朝晖; 林毅清;

【Author】 Qi Guozhen Wang Zhaohui Lin Yiqing (Department of Fine Chemical Engineering, East China University of Science and Technology,Shanghai,200237)

【机构】 华东理工大学精细化工系;

【摘要】 通过重氮化、偶合、还原和烷基化反应合成了3个溴代苯并三唑类紫外线吸收剂,经红外光谱、核磁共振、质谱和元素分析等确证了结构,并测定了其吸收波长,实验发现引入溴原子使其紫外线吸收性能提高。

【Abstract】 Three type Ⅱ UV absorbers of brominated benzotriazols were prepared by diazotisation,coupling,reduction and alkylation. The structures of these new compounds were characterized by IR, NMR, MS and Elementary Analysis. The UV visible absorption of UV absorbers was also tested. The increase of their molar absorption coefficient and the red shift of their maximum wavelength were due to the bromide in their molecule structures.

【关键词】 紫外线吸收剂; 苯并三唑; 合成;
【Key words】 UV absorbers Benzotriazol Synthesis;
  • 【文献出处】 江苏化工 ,JIANGSU CHEMICAL INDUSTRY , 编辑部邮箱 ,1999年01期
  • 【分类号】TQ314.257
  • 【被引频次】7
  • 【下载频次】183
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