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丙烯腈与衣康酸的溶液共聚合
SOLUTION POLYMERIZ ATI 0N OF ACRYLON ITRILE WITH ITACONIC ACID
【Abstract】 In order to prepare a polymer solution for making carbon fibre precusor by wetspinning,solution polymerization of acrylonitrile ( A N) with itaconic acid ( I A) was carriedoutin D M S Ousing azobisisobutyronitrile ( A I B N) asinitiator. The effects of( A N+ I A) and A I B N concentration , A Nto I Aratio,temperature on conversion rate and molecular weightwere investigated . The polymerization ratein D M S O was 2 .6 time as fast at thatin D M F. The copolymers were characterized by I Rand N M Ranalysis.
【关键词】 丙烯腈;
衣康酸;
溶液聚合;
二甲基亚砜;
【Key words】 Acrylonitrile; Itaconic acid; Solution polymerization; Dimethylsulfoxid;
【Key words】 Acrylonitrile; Itaconic acid; Solution polymerization; Dimethylsulfoxid;
【基金】 国家自然科学基金
- 【文献出处】 高分子学报 ,ACTA POLYMERICA SINICA , 编辑部邮箱 ,1999年05期
- 【被引频次】25
- 【下载频次】326