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多元校正-动力学谱法同时测定铬、钼、钨

Simultaneous Determination of Cr( Ⅵ) , Mo( Ⅵ)and W( Ⅵ) by Multivariate Calibration and Kinetic Spectrum

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【作者】 张军延朱仲良邓子峰梅雨

【Author】 ZHANGjun - yan , ZHUZhong -liang, DENGZi-feng, MEIYu (Departmentof Chemistry, Tongji University , Shanghai200092 , China)

【机构】 同济大学化学系!上海200092

【摘要】 基于各组分动力学谱的差异, 以H2O2 氧化KI为指示反应, 对Cr( Ⅵ) 、Mo( Ⅵ) 和W( Ⅵ)进行了同时测定. 铂电极被用作指示物质I-3 的指示电极, 装备有AD卡的奔腾电脑被用来同步记录动力学过程. 主成分回归法被用以建模并预报未知混合样品.

【Abstract】 Based on the difference in kinetic spectra, a method forthe simultaneous determina tion of Cr( Ⅵ), Mo( Ⅵ)and W( Ⅵ)is proposed by meansof multivariatecalibration .Theredox between KIand H2O2 wasemployed asan indicatorreaction and citric acid asan assistantagent. The kinetic process was synchronously recorded by a computer equipped with an ADcard and platinum electrode as an indicator electrode of I-3 which is an indicator in this system .Principal componentregressionisemployed to create the modeland predict unknown mixed samples.

  • 【文献出处】 福州大学学报(自然科学版) ,JOURNAL OF FUZHOU UNIVERSITY(NATURAL SCIENCES EDTION) , 编辑部邮箱 ,1999年S1期
  • 【分类号】O657
  • 【被引频次】4
  • 【下载频次】40
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