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二茂铁修饰青椒籽碳糊电极测定抗坏血酸

Ferrocene Modified Green Pepper Seed Carbon Paste Bioelectrodes for the Determination of Ascorbic Acid

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【作者】 邓子峰; 朱仲良; 杨正炜; 李通化;

【Author】 Deng Zifeng, Zhu Zhongliang, Yang Zhengwei, Li Tonghua (Department of Chemistry, Tongji University, Shanghai 200092)

【机构】 同济大学化学系; 同济大学化学系 上海200092; 上海200092; 上海200092;

【摘要】 以二茂铁(Fe)作为电子传递介体,制成Fe修饰的青椒籽碳糊电极,研究了该电极的性能,用恒电位电流法测定了抗坏血酸的浓度并用于药物中抗坏血酸的含量分析,结果与药典法相符.

【Abstract】 A ferrocene modified green pepper seed carbon paste bioelectrode for the determination of ascorbic acid was described. The electrocatalytic behavior of the electrode was investigated. The electrode responded linearly to the ascorbic acid concentration in the range of 7.23 × 10-5 - 7.23 × 10-3 mol/L, response time was less than 10 s. The electrode has been used to determine the ascorbic acid in Vc tablet and the result was in good agreement with that of the pharmacopeia.

  • 【文献出处】 分析化学 ,Chinese Journal of Analytical Chemistry , 编辑部邮箱 ,1999年03期
  • 【分类号】O657.15
  • 【被引频次】38
  • 【下载频次】193
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