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电沉积Ni-Co梯度合金的研究

Study on Ni Co Gradient Alloy Electrodeposition

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【作者】 覃奇贤; 李要民; 封万起; 韩秀文; 张义成;

【Author】 Qin Qixian, Li Yaomin, Feng Wanqi, Han Xiuwen, Zhang Yicheng

【机构】 天津大学化工学院!天津300072; 天津高科新技术发展有限公司!天津300072;

【摘要】 在以氨基磺酸镍和氨基硫酸钴为主盐的电解液中,镍作阳极,p H= 4.0,55℃条件下,采用2 A/dm 2 的阴极电流密度,可以电沉积出钴含量随厚度而变化的 Ni Co 合金层。实验结果表明,随着通电量的增加,合金镀层中的钴含量不断下降。由镀层性能测试可以看出,随着通电量的增加,合金镀层的硬度降低,内应力减小。

【Abstract】 Ni Co alloy layer in which Co content is varied with thickness was electrodeposited in electrolyte containing nickel sulfamate and cobalt sulfamate as main salts and metallic nickel as anode at 55℃ and 2.0 A/dm 2 cathodic current density. The experimental results show that Co content in the alloy layer is decrease gradually with the increase in electricity passed through the electrolyte, i.e. with the increase in thickness of the alloy layer. It can be seen from the results of alloy layer property measurements that with the increase in electricity passed through the electrolyte the hardness of the alloy is lowered and the internal stress of the alloy is decreased.

【关键词】 Ni-Co合金; 梯度; 硬度; 内应力;
【Key words】 Ni Co alloy; gradient; hardness; internal stress;
  • 【文献出处】 电镀与精饰 ,PLATING AND FINISHING , 编辑部邮箱 ,1999年05期
  • 【分类号】TQ153.2
  • 【被引频次】9
  • 【下载频次】135
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