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南极拉斯曼丘陵莫愁湖和团结湖水中有机物剖析

ON THE ORGANIC COMPOUNDS IN WATER OF MOCHOU AND HEART LAKE IN LARSEMANN HILLS,ANTARCTICA

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【作者】 李植生陈旭东张银华梁小民王骥粱彦龄

【Author】 Li Zhisheng,Chen Xudong,Zhang Yinhua,Liang Xiaomin,Wang Ji and Liang Yanling(Institute of Hydrobiology,Chinese Academy of Sciences,Wuhan 430072,China)

【机构】 中国科学院水生生物研究所

【摘要】 本文给出了南极莫愁湖和团结湖水中有机物信息。在湖水中获得的121个化学组分中确定出93个有机化合物,其中包括正构烷烃、类异戊二烯烷烃、芳烃、多环芳烃、醇、醛、酮、酯、脂肪酸类及酞酸酯类等。其含量在0.027~4.79μg/L之间。湖水中检测出全球性有机物666、DDT和PCBs,浓度在0.012~0.356μg/L。

【Abstract】 ater samples of 100 liters were absorbed with XAD2 and XAD4 resin columns,eluted with organic solvents and concentrated to 0.3 mL. The extracts were detected by GC/MS and GC,and 93 compounds were identified.They are nalkane,lipid isopentadiene alkane,polycyclic aromatic,aromatic, carboxylic acid, alcohol, aldehyde, ketone, esters, phthalic esters, organochlorine pesticides and polychlorinated biphenyls. The concentration of organic substances varied in the range of 0.027 and 4.79 μg/L.The nalkanes were distributed in a series of carbon numbers from C10 and C26,Maximum peak of carbon was C11 and C22 in the lakes respectively with a strong evenodd predommauc.The ratio of pristane to phytane may be used to judge the oxidation or reduction in aquatic environment.The monocarboxylic acid is distributed in C12∶0,C14∶0,C16∶0 and the dominant carboxylic acid was the straight chained C12∶0(Decanoic acid).The distribution indicated that the sources of organic substances are mainly derived from organism.Content of Benzoic acid methylester is the highest in the organic substances and the concentrations are 4.79 and 3.28 μg/L in two waters respectively.Three kinds of phthalic esters,dibutyl phthalate,diisobutyl phthalate and diisooctyl phthalate were found and the concentrations are in the range of 0.071 and 0.597 μg/L.Organochlorine pesticides (666,DDT) and Polychlorinated biphenyls(PCBs) in water samples of Mochou Lake and Heart Lake were also analyzed. The results show that the concentrations are in range of 0.012 and 0.356 μg/L 666,DDT and PCBs were detected. Even though the concentrations are low,it means that some global pollutants have more or less exerted their influence on the Antarctic environment.

【基金】 国家自然科学基金
  • 【文献出处】 极地研究 ,CHINESE JOURNAL OF POLAR RESEARCH , 编辑部邮箱 ,1998年02期
  • 【分类号】P941.61
  • 【被引频次】3
  • 【下载频次】60
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