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部分水解聚(丙烯酸甲酯─醋酸乙烯酯─甲基丙烯酸甲酯)多孔载体合成与结构的研究

STUDIES ON SYNTHESIS AND STRUCTURE OF PARTIALLY HYDROLYZED POLY (MERTHYL ACRYLATE-VINYL ACETATE -METHYL METHACRYLATE) AS CARRIER

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【作者】 张洁辉吴中兴郑邦乾

【Author】 Zhang Jiehui; Wu Zhongxing; Zheng Bangqian (Polymer Research Institute, Sichuan Union University, Chaengdu, 610065 )

【机构】 四川联合大学高分子研究所!成都610065

【摘要】 该文以二乙烯苯和双丙烯酸多缩乙二醇酯为交联剂,制备了部分水解聚(丙烯酸甲酯-醋酸乙烯酯-甲基丙烯酸甲酯)多孔载体。用电镜、压汞仪、红外、X射线衍射仪等测定了载体的结构与孔结构。

【Abstract】 A partially hydrolyzed poly(methyl acrylate -vinyl acetate - methyl methacrylate) has been prepared with DVB and EGDA as crosslinking agent and polyvinyl acetate as porogenic agent by suspension polymerization, followed by a hydrolysis process. This copolymer can be used as a porous carrier for microorganism. The mechanism of pore - structure formation of the copolymer carrier and the dependence of the pore - structure on the polymerization conditions were discussed. The structure and pore - structure of the copolymer carrier were examined by SEM, X ray and mercury porosimetry, and related to the composition of and the extent of crosslinking of the copolymer.

【基金】 国家自然科学基金
  • 【文献出处】 离子交换与吸附 ,ION EXCHANGE AND ADSORPTION , 编辑部邮箱 ,1997年03期
  • 【分类号】TQ424
  • 【被引频次】1
  • 【下载频次】137
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