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中性红的电化学反应研究
STUDY ON ELECTROCHEMICAL REACTION OF NEUTRAL RED
【摘要】 利用电势阶跃法和光谱电化学方法研究了中性红的氧化还原反应,并测定出标准电极电势E=0258(vsNHE),电子转移数n=2以及还原态离解常数pKa1=518,pKa2=603,推测了中性红在水溶液及非水溶液(二甲亚砜)中的电极反应机理
【Abstract】 The electrochemical redox of neutral red has been studied by potential step method and thin layer spectroelectrochemistry The standard potential E and the number of electron transfer determined were 0 258V(vs NHE)and 2 respectively The acid dissocilation constants for the reducted neutral red were obtained as pK a1 =5 18,pK a2 =6 03 The mechanism of electrode reaction has been proposed
【关键词】 薄层光谱电化学;
电势阶跃;
中性红;
【Key words】 thin layer spectrolelectrochemistry; potential step; neutral red;
【Key words】 thin layer spectrolelectrochemistry; potential step; neutral red;
【基金】 山东省自然科学基金资助项目
- 【文献出处】 山东建材学院学报 ,JOURNAL OF SHANDONG INSTITUTE OF BUILDING MATERIALS , 编辑部邮箱 ,1996年02期
- 【分类号】O646.2
- 【被引频次】4
- 【下载频次】158