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三次样条插值离子选择电极测定人发中的氟和碘

Determination of Fluorine and Iodine in Human Hair by lon-Selective Electrodes with Cubic Spline Interpolation

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【作者】 张凤君张野赵淑洁

【Author】 Zhang Fengjun; Zhang Ye; Zhao Shujie (Department of Applied Chemistry, Changchun University of Earth Science,130026)

【机构】 长春地质学院应化系

【摘要】 对同时测定同一底液中的氟和碘进行了探讨,找到了合适的1.0mol/L柠檬酸钠-1.0mol/LNaNO3pH=5.5的缓冲体系。采用三次样条插值程序可很好地解决曲线的弯曲问题,改善了含氟和碘量低分析结果的准确度、精密度及检测下限。

【Abstract】 Determination of flurine and iodine in a Single solution of human hair samples with ionselective electrodes has been investigated.It was found that a buffer system of 1.0 mol/L sodium citrate-1.0 mol/L sodium nitrate at pH 5.5 was the best for this method. At lower concentrations, the accuracy, precision and limit of detection of the method can be much improved by using a program of cubic spline interpolation for the non-linear portion of the calibration curve.

  • 【文献出处】 分析测试学报 ,JOURNAL OF INSTRUMENTAL ANALYSIS , 编辑部邮箱 ,1994年03期
  • 【分类号】Q581
  • 【被引频次】4
  • 【下载频次】45
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