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三次样条插值离子选择电极测定人发中的氟和碘
Determination of Fluorine and Iodine in Human Hair by lon-Selective Electrodes with Cubic Spline Interpolation
【摘要】 对同时测定同一底液中的氟和碘进行了探讨,找到了合适的1.0mol/L柠檬酸钠-1.0mol/LNaNO3pH=5.5的缓冲体系。采用三次样条插值程序可很好地解决曲线的弯曲问题,改善了含氟和碘量低分析结果的准确度、精密度及检测下限。
【Abstract】 Determination of flurine and iodine in a Single solution of human hair samples with ionselective electrodes has been investigated.It was found that a buffer system of 1.0 mol/L sodium citrate-1.0 mol/L sodium nitrate at pH 5.5 was the best for this method. At lower concentrations, the accuracy, precision and limit of detection of the method can be much improved by using a program of cubic spline interpolation for the non-linear portion of the calibration curve.
【关键词】 三次样条插值;
【Key words】 Cubic spline interpolation; Ion-selective electrodes; Fluorine; Iodine; Human hair.;
【Key words】 Cubic spline interpolation; Ion-selective electrodes; Fluorine; Iodine; Human hair.;
- 【文献出处】 分析测试学报 ,JOURNAL OF INSTRUMENTAL ANALYSIS , 编辑部邮箱 ,1994年03期
- 【分类号】Q581
- 【被引频次】4
- 【下载频次】45