【摘要】 本文研究机械搅拌反应釜内三相淤浆床甲醇合成的宏观反应动力学，反应压力５ＭＰａ，反应温度为２１０～２５０℃，采用０．１２５～０．１５４ｍｍ（１００目～１２０目）Ｃ３０１铜基甲醇合成催化剂，食品级液体石蜡作惰性液相介质，反应气体含ＣＯ、ＣＯ＿２、Ｈ＿２、Ｎ＿２及ＣＨ＿４，搅拌器转速９５０ｒ／ｍｉｎ。实验测定宏观反应动力学数据，应用改进高斯－牛顿法参数估值，获得宏观动力学方程。更多还原

【Abstract】 The global kinetics of methanol synthesis from carbon monoxide,carbon dioxideand hydrogen was investigated in a three phase slurry reactor with mechanical agitator, Re-action conditions were as follows :pressure 5 MPa,temperature 210～250℃,catalyst size 0. 125～0.154mm（100～120mesh）, liquid paraffin as inert liquid phase and speed of agitator950 r/min. Methanol concentration in the gaseous product was in general equal to 7～8percent, being higher than that in the traditional gas- solid catalytic process. By the improvedGauss-Newton method, Langmuir-Hinshelwood type global kinetic models of the parallelhydrogenation of CO and CO₂ have been developed in terms of fugacities of reaction components.更多还原