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抗氧剂2246在BR生产中的应用

APPLICATION OF ANTIOXIDANT 2246 IN cis-,4-POLYBUTADIENE PRODUCTION

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【作者】 张萍杨清华史翠花武玉斌唐学明

【Author】 Zhang Ping;Yang Qinghua;Shi Cuihua;Wu Yubin and Tang Xueming(Department of Rubber Engineering, Qingdao Institute of Chemical Technology)

【机构】 青岛化工学院橡胶工程系

【摘要】 分析了抗氧剂2246对BR的稳定化作用,并与抗氧剂2246的稳定效能进行了比较。结果表明,抗氧剂2246和抗氧剂264用量相同时,前者使BR的氧化诱导期延长,氧化温度提高,热氧老化性能改善,且耐候性、加工稳定性都明显变好。采用0.6%抗氧剂2246,即可达到或超过1.1%抗氧剂264的效能,并能满足BR贮存3a及在运输、加工过程中性能稳定不变的要求。

【Abstract】 The xtabilization of antioxidant 2246 in the production of cis-1,4-polybutadiene rubber (BR) was investigated and compared with that of antioxidant 264. The results showed that the BR containing antioxidant 2246 had higher oxidation temperature, longer oxidation induction period,more stable processing stability and better ability of thermal-oxidative aging and weathering resistance in contrasted with those Of BR containing the same amount of antioxidant 264.The BR containing 0.6% of antioxidant 2246 had better aging resistance ability than that of BR containing 1.1% antioxidant 264, and reached the requirement of stability in the store,transportation and processing of BR.

  • 【文献出处】 合成橡胶工业 ,CHINA SYNTHETIC RUBBER INDUSTRY , 编辑部邮箱 ,1994年04期
  • 【分类号】TQ333.2
  • 【被引频次】14
  • 【下载频次】186
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