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加氢甲酰化法合成醛类香料

synthesis of perfumery aldehydes by hydroformylation

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【作者】 王乐夫; 黄仲涛;

【Author】 Wang Lefu Huang Zhongtao(Department of Chemical Engineering,SouthChina University of Technology,Guangzhou510641)

【机构】 华南理工大学化学工程系;

【摘要】 评述了烯烃加氢甲酰化过程的基本原理,并着重介绍了在温和的反应条件下,各种萜烯及其相关分子的加氢甲酰化。对于反应中所用的催化剂以及烯烃结构的影响也作了综述。

【Abstract】 Many valuable perfumery aldehydes can be synthesized by the hydroformylation of olefins which is potentially one of the least expensive synthetic methods. The basic principle for the hydro-formylation of olefins is reviewed,and the hydro-formylation of various terpenes and related molecules under mild conditions are particularly involved. The catalysts used in the reactions and the effect of olefin structure are also summarized.

【关键词】 加氢甲酰化; 烯烃; 萜烯; 醛; 香料;
【Key words】 hydroformylation; olefin; terpene; aldehyde; perfumery;
  • 【文献出处】 天然气化工(C1化学与化工) ,Natural Gas Chemical Industry , 编辑部邮箱 ,1993年03期
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